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81.
Short malonyl dehydro peptides have been epoxidized using H2O2/Na2WO4 dihydrate. The obtained diastereomeric epoxides were separated by HPLC and successfully tested in the ring opening reaction with N-Boc l-cysteine methyl ester, to indicate their electrophilic behavior. Moreover, by a simple two-step reaction, the epoxy malonyl peptides can be converted into the corresponding aziridino malonyl peptides. 相似文献
82.
Andrea Amar Dr. Bernhard Blümich Prof. Dr. Federico Casanova Dr. 《Chemphyschem》2010,11(12):2630-2638
A new, fast magnetic resonance imaging (MRI) method is described and applied to map flow fields in systems with internal velocities rapidly varying along the streamlines. While conventional MRI techniques encode the velocity information in a preparatory period prior to the imaging acquisition module, our technique repeatedly refreshes the velocity encoding during a single‐shot imaging sequence. In this way, the maximum acceleration responsible for velocity variation of the molecules is increased by up to two orders of magnitude compared to standard procedures. Besides being compatible with high acceleration, this pulse sequence is suited to acquiring in a single scan the multiple velocity images required to construct a full velocity vector map. The power of this new methodology is demonstrated by following the internal dynamics of toluene droplets levitating in a counterflow of water during mass transfer of acetone from the water phase into the drop in the presence of surface‐active impurities. The dramatic reduction in measurement time allows visualization for the first time of the important impact of even small concentrations of acetone on accumulation of surfactants at the drop’s surface. 相似文献
83.
Tagliazucchi M Williams FJ Calvo EJ 《Chemical communications (Cambridge, England)》2010,46(47):9004-9006
We present polyelectrolyte multilayer modified electrodes exhibiting novel chemically responsive redox behaviour due to the combination of both redox and metal-ion-ligand functionalities on the same sites. 相似文献
84.
A reversed-phase high-performance liquid chromatographic method for the determination of benzydamine hydrochloride and its impurities 3-dimethylaminopropyl 2-benzylaminobenzoate, 3-dimethylaminopropyl-2-aminobenzoate,1-benzyl-1H-indazol-3-ol, 1-benzyl-2-(3-dimethylaminopropyl)-1,2-dihydro-3H-indazol-3-one, and 1-benzyl-3-(3-(3-dimethylaminopropyl)-3-methylamino)propoxy-(1)H-indazole in a collutory formulation is developed. The separation is carried out on a Gemini C(18) (250 × 4.6 mm, 5 μm) column using acetonitrile-methanol-ammonium carbonate buffer (10 mM; pH 10.5) (37.5:37.5:25, v/v/v) as mobile phase at a flow rate of 1.0 mL/min, column temperature 30°C, and UV detection at 218 nm. Famotidine is used as an internal standard. The total run-time is less than 15 min. The analytical curves present coefficients of correlation greater than 0.99, and detection limits are calculated for all analytes. Excellent accuracy and precision are obtained for benzydamine hydrochloride. Recoveries vary from 98.25 to 102.8%, and intra- and inter-day precisions, calculated as the percent relative standard deviation, are lower than 2.2%. Specificity and robustness for benzydamine hydrochloride are also determined. The method allows the quantitative determination of benzydamine hydrochloride and its impurities, and it is suitable for routine analysis in quality control laboratories. 相似文献
85.
Federico Liberatore Giovanni Righini Matteo Salani 《4OR: A Quarterly Journal of Operations Research》2011,9(1):49-82
The Vehicle Routing Problem with Time Windows consists of computing a minimum cost set of routes for a fleet of vehicles of
limited capacity visiting a given set of customers with known demand, with the additional constraint that each customer must
be visited in a specified time window. We consider the case in which time window constraints are relaxed into “soft” constraints,
that is penalty terms are added to the solution cost whenever a vehicle serves a customer outside of his time window. We present
a branch-and-price algorithm which is the first exact optimization algorithm for this problem. 相似文献
86.
A combined experimental and first principles study of Cu defects in bulk ZnO is presented. Cu particles are epitaxially deposited on the polar O-ZnO(0001) surface at room temperature. Upon heating, a broadening of the quasielastic peak in high resolution electron energy loss spectra is observed, corresponding to an electronic doping effect of Cu atoms in bulk ZnO with an ionization energy of 88 meV. Cu impurities in ZnO, although commonly acting as acceptors, are presently observed to induce shallow donor states. We assign these to interstitial Cu species on the basis of a hybrid density functional study. 相似文献
87.
Luca Pasquini Elsa Callini Matteo Brighi Federico Boscherini Amelia Montone Torben R. Jensen Chiara Maurizio Marco Vittori Antisari Ennio Bonetti 《Journal of nanoparticle research》2011,13(11):5727-5737
We report on the hydrogen storage behaviour of Mg nanoparticles (NPs) (size range 100 nm–1 μm) with metal-oxide core–shell
morphology synthesized by inert gas condensation and decorated by transition metal (TM) (Pd or Ti) clusters via in situ vacuum
deposition. The structure and morphology of the as-prepared and hydrogenated NPs is studied by electron microscopy, X-ray
diffraction including in situ experiments and X-ray absorption spectroscopy, in order to investigate the relationships with
the hydrogen storage kinetics measured by the volumetric Sieverts method. With both Pd and Ti, the decoration deeply improves
the hydrogen sorption properties: previously inert NPs exhibit complete hydrogenation with fast transformation kinetics, good
stability and reversible gravimetric capacity that can attain 6 wt%. In the case of Pd-decoration, the occurrence of Mg–Pd
alloying is observed at high temperatures and in dependence of the hydrogen pressure conditions. These structural transformations
modify both the kinetics and thermodynamics of hydride formation, while Ti-decoration has an effect only on the kinetics.
The experimental results are discussed in relation with key issues such as the amount of decoration, the heat of mixing between
TM and Mg and the binding energy between TM and hydrogen. 相似文献
88.
Alessandro Lo Giudice Paolo Olivero Claudio Manfredotti Marco Marinelli Enrico Milani Federico Picollo Giuseppe Prestopino Alessandro Re Valentino Rigato Claudio Verona Gianluca Verona‐Rinati Ettore Vittone 《固体物理学:研究快报》2011,5(2):80-82
In order to evaluate the charge collection efficiency (CCE) profile of single‐crystal diamond devices based on a p‐type/intrinsic/metal configuration, a lateral Ion Beam Induced Charge (IBIC) analysis was performed over their cleaved cross sections using a 2 MeV proton microbeam. CCE profiles in the depth direction were extracted from the cross‐sectional maps at variable bias voltage. IBIC spectra relevant to the depletion region extending beneath the frontal Schottky electrode show a 100% CCE, with a spectral resolution of about 1.5%. The dependence of the width of the high efficiency region from applied bias voltage allows the constant residual doping concentration of the active region to be evaluated. The region where the electric field is absent shows an exponentially decreasing CCE profile, from which it is possible to estimate the diffusion length of the minority carriers by means of a drift–diffusion model. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
89.
This paper provides a new model of network formation that bridges the gap between the two benchmark game-theoretic models by Bala and Goyal (2000a) – the one-way flow model, and the two-way flow model – and includes both as limiting cases. As in both the said models, a link can be initiated unilaterally by any player with any other in what we call an “asymmetric flow” network, and the flow through a link towards the player who supports it is perfect. Unlike those models, there is friction or decay in the opposite direction. When this decay is complete there is no flow and this corresponds to the one-way flow model. The limit case when the decay in the opposite direction (and asymmetry) disappears corresponds to the two-way flow model. We characterize stable and strictly stable architectures for the whole range of parameters of this “intermediate” and more general model. A study of the efficiency of these architectures shows that in general stability and efficiency do not go together. We also prove the convergence of Bala and Goyal’s dynamic model in this context. 相似文献
90.
Salvatore Federico Paul Gassiat 《Journal of Optimization Theory and Applications》2014,160(3):966-991
We study a problem of optimal investment/consumption over an infinite horizon in a market consisting of a liquid and an illiquid asset. The liquid asset is observed and can be traded continuously, while the illiquid one can only be traded and observed at discrete random times corresponding to the jumps of a Poisson process. The problem is a nonstandard mixed discrete/continuous optimal control problem, which we face by the dynamic programming approach. The main goal of the paper is the characterization of the value function as unique viscosity solution of an associated Hamilton–Jacobi–Bellman equation. We then use such a result to build a numerical algorithm, allowing one to approximate the value function and so to measure the cost of illiquidity. 相似文献